Comparative studies of Al-doped ZnO and Ga-doped ZnO transparent conducting oxide thin films

被引:0
作者
Min-Chul Jun
Sang-Uk Park
Jung-Hyuk Koh
机构
[1] Kwangwoon University,Department of Electronic Materials Engineering
来源
Nanoscale Research Letters | / 7卷
关键词
AZO; GZO; Transparent conducting oxide; Thin films; Spin-coating;
D O I
暂无
中图分类号
学科分类号
摘要
We have investigated the influences of aluminum and gallium dopants (0 to 2.0 mol%) on zinc oxide (ZnO) thin films regarding crystallization and electrical and optical properties for application in transparent conducting oxide devices. Al- and Ga-doped ZnO thin films were deposited on glass substrates (corning 1737) by sol–gel spin-coating process. As a starting material, AlCl3⋅6H2O, Ga(NO3)2, and Zn(CH3COO)2⋅2H2O were used. A lowest sheet resistance of 3.3 × 103 Ω/□ was obtained for the GZO thin film doped with 1.5 mol% of Ga after post-annealing at 650°C for 60 min in air. All the films showed more than 85% transparency in the visible region. We have studied the structural and microstructural properties as a function of Al and Ga concentrations through X-ray diffraction and scanning electron microscopy analysis. In addition, the optical bandgap and photoluminescence were estimated.
引用
收藏
相关论文
共 119 条
[21]  
Sun C(2005)Fabrication and characterization of high quality undoped and Ga2O3-doped ZnO thin films by reactive electron beam co-evaporation technique J Cryst Growth 275 512-undefined
[22]  
Gong J(2002)Effect of vacuum annealing on the properties of transparent conductive AZO thin films prepared by dc magnetron sputtering Phys Status Solidi A 193 139-undefined
[23]  
Huang RF(1998)Al-doped zinc oxide films deposited by simultaneous rf and dc excitation of a magnetron plasma: relationships between plasma parameters and structural and electrical film properties J Appl Phys 83 1087-undefined
[24]  
Wen LS(1992)Textured aluminum-doped zinc oxide thin films from atmospheric pressure chemical‐vapor deposition J Appl Phys 72 5381-undefined
[25]  
Gordon RG(1990)Growth and characterization of tin oxide films prepared by chemical vapour deposition Thin Solid Films 190 287-undefined
[26]  
Nishino J(1954)Anomalous optical absorption limit in InSb Phys Rev 93 632-undefined
[27]  
Kawarada T(1954)The interpretation of the properties of indium antimonide Proc Phys Soc Lond B 67 775-undefined
[28]  
Ohshio S(1966)Optical properties and electronic structure of amorphous germanium Phys Stat Sol 15 627-undefined
[29]  
Saitoh H(2008)Effect of oxygen on the optical and the electrical properties of amorphous InGaZnO thin films prepared by rf magnetron sputtering J Kor Phys Soc 53 2019-undefined
[30]  
Maruyama K(1998)High temperature excitonic stimulated emission from ZnO epitaxial layers Appl Phys Lett 73 1038-undefined