The Interaction of β-Cyclodextrin with Benzoic Acid

被引:0
作者
L. A. Belyakova
A. M. Varvarin
O. V. Khora
E. I. Oranskaya
机构
[1] National Academy of Sciences of Ukraine,Institute of Surface Chemistry
来源
Russian Journal of Physical Chemistry A, Focus on Chemistry | 2008年 / 82卷
关键词
Benzoic Acid; Cyclodextrin; Inclusion Complex; Differential Thermal Analysis Curve; Mechanical Mixture;
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学科分类号
摘要
The interaction of β-cyclodextrin with benzoic acid was studied by UV and IR spectroscopy, X-ray diffraction, and thermogravimetry. The introduction of the benzoic acid molecule into the internal hydrophobic β-cyclodextrin cavity and additional stabilization by weak H-bonds caused the formation of 1: 1 axial inclusion complexes of the host—guest type. The degree of crystallinity of the inclusion complex decreased compared with the initial compounds, whereas its thermal stability increased.
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页码:228 / 232
页数:4
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