Hydrogenation of (–)-Menthone, (+)-Isomenthone, and (+)-Pulegone with Platinum/Tin Catalysts

被引：0
|
作者：
Virginia Vetere
Gerardo F. Santori
Albertina Moglioni
Graciela Y. Moltrasio Iglesias
Mónica L. Casella
Osmar A. Ferretti
机构：
[1] CINDECA (UNLP-CONICET),Facultad de Farmacia y Bioquímica, UBA
[2] Facultad de Ingeniería de la UNLP,undefined
[3] Departamento de Química Orgánica,undefined
来源：
Catalysis Letters | 2002年 / 84卷
关键词：
hydrogenation; menthol isomers; platinum/tin catalysts; surface organometallic chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The hydrogenation of (-)-menthone, (+)-isomenthone, and (+)-pulegone over SiO2-supported Pt and Pt-Sn catalysts was studied in this work. The modification with tin was performed by means of the techniques of surface organometallic chemistry on metals. This way of modifying the catalysts allowed stereoisomers of menthol to be obtained in a one-step process. The hydrogenation of these terpenones was favored by the presence of tin in the bimetallic phase.
引用
收藏
页码：251 / 257
页数：6
相关论文
共 50 条
  • [1] Hydrogenation of (-)-menthone, (+)-isomenthone, and (+)-pulegone with platinum/tin catalysts
    Vetere, V
    Santori, GF
    Moglioni, A
    Iglesias, GYM
    Casella, ML
    Ferretti, OA
    CATALYSIS LETTERS, 2002, 84 (3-4) : 251 - 257
  • [2] Stereoselective hydrogenation of (-)-menthone and (+)-isomenthone mixture using nickel catalysts
    Kukula, P.
    Červený, L.
    2000, VSP BV (26)
  • [3] Stereoselective hydrogenation of (-)-menthone and (+)-isomenthone mixture using nickel catalysts
    Kukula, P
    Cerveny, L
    RESEARCH ON CHEMICAL INTERMEDIATES, 2000, 26 (09) : 913 - 922
  • [4] Stereoselective hydrogenation of (−)-menthone and (+)-isomenthone mixture using nickel catalysts
    Pavel Kukula
    Libor Červený
    Research on Chemical Intermediates, 2000, 26 : 913 - 922
  • [5] The kinetics of stereoselective hydrogenation of (-)-menthone and (+)-isomenthone mixture using nickel catalysts
    Kukula, P
    Cerveny, L
    APPLIED CATALYSIS A-GENERAL, 2000, 193 (1-2) : 285 - 290
  • [6] STEREOSELECTIVE HYDROGENATION OF A MENTHONE-ISOMENTHONE MIXTURE ON HETEROGENEOUS NICKEL, NICKEL-COBALT, AND COBALT CATALYSTS
    ZUBAREVA, ND
    KLABUNOVSKII, EI
    KHEIFITS, LA
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1989, 38 (08): : 1765 - 1768
  • [7] Biogenetic studies in Mentha x piperita.: 2.: Stereoselectivity in the bioconversion of pulegone into menthone and isomenthone
    Fuchs, S
    Beck, T
    Sandvoss, M
    Mosandl, A
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1999, 47 (08) : 3058 - 3062
  • [8] PREPARATION OF ISOMENTHONE FROM MENTHONE
    LIANG, LY
    HABARA, T
    DOI, M
    SHUTO, Y
    KINOSHITA, Y
    AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1989, 53 (09): : 2517 - 2518
  • [9] BENZENE HYDROGENATION ON PLATINUM - TIN BIMETALLIC CATALYSTS
    CAMPERO, A
    RUIZ, M
    GOMEZ, R
    REACTION KINETICS AND CATALYSIS LETTERS, 1976, 5 (02): : 177 - 182
  • [10] Stereoselectivity of electroreduction of a menthone-isomenthone mixture
    N. D. Zubareva
    A. A. Vedenyapin
    E. I. Klabunovskii
    Russian Journal of Applied Chemistry, 2009, 82 : 1234 - 1237
12345