Terpyridine Metal Complexes as Building Blocks for Supramolecular Assemblies and Polymers: Thermal Stabilities and Thin Film Preparation

被引：0

作者：

Ulrich S. Schubert

Christian Eschbaumer

Qingrui An

Tim Salditt

机构：

[1] Lehrstuhl für Makromolekulare Stoffe,

[2] Technische Universität München,undefined

[3] Sektion Physik der Ludwig-Maximilians-Universität München,undefined

来源：

Journal of inclusion phenomena and macrocyclic chemistry | 1999年 / 35卷

关键词：

terpyridine; metal complexes; thermal stability; thin film preparation; supramolecular systems;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

5,5''-Dimethyl-2,2':6',2''-terpyridine complexes with various transition metal ions like Zn(II), Co(II), Mn(II) and Hg(II) were investigated concerning their thermal properties. A significant dependency of the thermal stability (5% weight loss) of the complexes depending on the kind of metal ion used could be observed ranging from 315 to 390 °C. Furthermore, self-assembled thin films of such metallo-supramolecular Hg(II) complexes were prepared and characterized by synchrotron based X-ray reflectivity and fluorescence techniques.

引用

页码：35 / 43

页数：8

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