Terpyridine Metal Complexes as Building Blocks for Supramolecular Assemblies and Polymers: Thermal Stabilities and Thin Film Preparation

被引：0
|
作者：
Ulrich S. Schubert
Christian Eschbaumer
Qingrui An
Tim Salditt
机构：
[1] Lehrstuhl für Makromolekulare Stoffe,
[2] Technische Universität München,undefined
[3] Sektion Physik der Ludwig-Maximilians-Universität München,undefined
来源：
Journal of inclusion phenomena and macrocyclic chemistry | 1999年 / 35卷
关键词：
terpyridine; metal complexes; thermal stability; thin film preparation; supramolecular systems;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
5,5''-Dimethyl-2,2':6',2''-terpyridine complexes with various transition metal ions like Zn(II), Co(II), Mn(II) and Hg(II) were investigated concerning their thermal properties. A significant dependency of the thermal stability (5% weight loss) of the complexes depending on the kind of metal ion used could be observed ranging from 315 to 390 °C. Furthermore, self-assembled thin films of such metallo-supramolecular Hg(II) complexes were prepared and characterized by synchrotron based X-ray reflectivity and fluorescence techniques.
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页码：35 / 43
页数：8
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