Calculation of the temperature distribution at the HPHT growing of diamond single crystals in cells with two growth layers

被引:0
作者
A. V. Burchenia
V. V. Lysakovs’kii
S. O. Gordeyev
S. O. Ivakhnenko
A. M. Kutsai
O. M. Suprun
机构
[1] National Academy of Sciences of Ukraine,Bakul Institute for Superhard Materials
来源
Journal of Superhard Materials | 2017年 / 39卷
关键词
diamond; temperature gradient method; finite element method; high-pressure apparatus; distribution of the temperatures; IR spectroscopy;
D O I
暂无
中图分类号
学科分类号
摘要
Finite element method was used to calculate the distribution of temperatures in growth cells of the toroid TC-40 -type HPA. The experimental investigations of the process of growing type IIa diamond single crystals were performed in high-pressure cells with two growth layers. It is shown that in using the cell materials having appropriate properties and defined configuration of the system of the resistive heating the temperature gradients are 5.4–5.6°C/mm and the growth rate is 2.46 mg/h. The total weight of obtained structurally perfect type IIa diamond single crystals in the upper and lower growth layers is 1.18 and 1.13 carats, respectively, the nitrogen content in all grown crystals is 1–3 ppt.
引用
收藏
页码:149 / 154
页数:5
相关论文
共 21 条
[1]  
Strong H.M.(1972)The growth of large diamond crystals J. Naturwisenschaften 1 1-7
[2]  
Wentorf R.H.(1990)Growing of large diamond crystals on the “split sphere” type apparatuses without presses Dokl. USSR Acad. Sci. 315 1221-1224
[3]  
Pal’yanov Yu.(2015)Problems of seed-growing diamond single crystals with the use of hexadie high-pressure apparatuses of large volume in Porodorazrushayushchii i metalloobrabatyvayushchii instrument—tekhnika i technologiya ego izgotovleniya i primeneniya (Rock destruction and metal-working tools—techniques and technology of the tool production and applications), Collect. Papers, Kiev: Bakul’ ISM, Nat. Ac. Sci. Ukraine 17 191-203
[4]  
Malinovsky I.Yu.(2015)Growth kinetics of diamond single crystals in a hexadie high-pressure apparatus Ibid. 17 209-213
[5]  
Borzdov Yu.M.(1996)Morphology of diamond crystals synthesized in wide ranges of temperatures and pressures in Proc. All-USSR Mineral. Society 1 33-36
[6]  
Lysakovs’kii V.V.(1983)Modeling of electrical temperature fields and the fields of thermotensions in HPA by finite element method, Superhard Mater. 3 3-8
[7]  
Lysakovs’kii V.V.(2010)Computational modelling of superhard materials synthesis Comp. Mater. Sci. 49 85-94
[8]  
Novikov N.V.(1994)A defect concentration in diamond Phil. Mag. B. 69 1149-1153
[9]  
Nagornyi V.V.(undefined)undefined undefined undefined undefined-undefined
[10]  
Bezrukov V.A.(undefined)undefined undefined undefined undefined-undefined