Lanthanide Liquid Crystalline Complexes with Perfluoroalkylsulfate Anion

被引：0
|
作者：
F. K. Gainullina
L. V. Malykhina
L. M. Tinchurina
G. I. Ivanova
K. Binnemans
Yu. G. Galyametdinov
机构：
[1] Zavoiskii Physicotechnical Institute, Kazan Scientific Center, Russian Academy of Sciences, Kazan, 420029 Tatarstan
[2] Kazan State Technological University, Kazan, Tatarstan
[3] Catholic University, Leuven
来源：
Russian Journal of Coordination Chemistry | 2003年 / 29卷 / 5期
基金：
俄罗斯基础研究基金会;
关键词：
Microscopy; Physical Chemistry; Differential Scanning Calorimetry; Calorimetry; Liquid Crystal;
D O I：
10.1023/A:1023684003693
中图分类号：
学科分类号：
摘要：
Lanthanide complexes L3″ Ln(ROSO3)3 are synthesized with Ln(III) = Eu, Tb, Dy, Ho, Er, Tm, Yb; L″ = 4-tetradecyloxy-N-octadecyl-2-hydroxybenzaldimine and perfluoro-substituted alkylsulfate anion as counterion (where R = CF3(CF2) 8CH2). Their IR spectra are described. The synthesized compounds are studied by the polythermal polarizing microscopy and differential scanning calorimetry. The title complexes are thermotropic liquid crystals that exhibit smectic SA mesophase.
引用
收藏
页码：357 / 361
页数：4
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