Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole: Synthesis and study

被引：0

作者：

M. B. Bushuev

A. V. Virovets

D. Yu. Naumov

Yu. G. Shvedenkov

L. A. Sheludyakova

V. N. Elokhina

E. G. Boguslavsky

L. G. Lavrenova

机构：

[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division

[2] Russian Academy of Sciences,Irkutsk Institute of Chemistry, Siberian Division

来源：

Russian Journal of Coordination Chemistry | 2006年 / 32卷

关键词：

Physical Chemistry; Inorganic Chemistry; Triazole; Exchange Interaction; Antiferromagnetic Exchange;

D O I：

暂无

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学科分类号：

摘要：

The Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole (L) of the composition CuLA2 · H2O (A = Cl−, Br−), CuL2A2 (A = Cl−, Br−, NO3−), CoL2A2 · nH2O (A = Cl−, n = 1; A = NCS−, n = 0) are synthesized. In these complexes, the ligand L is coordinated to a metal in monodentate mode through the heterocyclic N(1) atom. The Cu: L = 1: 1 complexes have binuclear structures with the anions acting as bridges, whereas the M: L = 1: 2 complexes are mononuclear. Both ferro-and antiferromagnetic exchange interactions are detected for the synthesized complexes.

引用

页码：309 / 320

页数：11