Compressibility, phase transitions and amorphization of coronene at pressures up to 6 GPa

被引:0
作者
A. D. Chanyshev
A. Yu. Likhacheva
P. N. Gavryushkin
K. D. Litasov
机构
[1] Russian Academy of Sciences,Sobolev Institute of Geology and Mineralogy, Siberian Branch
[2] Novosibirsk National Research State University,Budker Institute of Nuclear Physics, Siberian Branch
[3] Russian Academy of Sciences,undefined
来源
Journal of Structural Chemistry | 2016年 / 57卷
关键词
high pressure X-ray diffraction; diamond anvil cell; coronene; compressibility;
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摘要
The work is devoted to the experimental study of coronene C24H12 at high pressure and room temperature using in situ X-ray diffraction in a diamond anvil cell. The high-pressure phase P2/m of coronene was found at 0.9 GPa, the PV-equation of state for P2/m coronene phase was defined to 4 GPa: K0 = 10.8(3) GPa, K0′ = 7. At 5.9 GPa partial amorphization of coronene was observed. After the decompression to ambient pressure the high-pressure phase P2/m was preserved, that can be related with partial amorphization.
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页码:1489 / 1492
页数:3
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