1,3,5-Trimethyl-1,3,5-tris(hexafluoroalkyl)cyclotrisiloxanes. Basicity of ethoxysilanes and cyclosiloxanes

被引：0

作者：

Yu. V. Khoroshavina

G. A. Nikolaev

机构：

[1] Federal State Unitary Enterprise “Lebedev Research Institute of Synthetic Rubber,

[2] ”,undefined

来源：

Russian Journal of General Chemistry | 2011年 / 81卷

关键词：

Siloxane; Cationic Polymerization; Heptyl; Siloxane Bond; Trisiloxane;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

1,3,5-Trimethyl-1,3,5-tris(hexafluoroalkyl)cyclotrisiloxanes were synthesized by hydrolytic polycondensation of methyl(hexafluoroalkyl)dichlorosilanes, and 1,1,3,3,5-pentamethyl-5-(trifluoromethyltrifluorobicyclo[2.2.1]heptyl)cyclotrisiloxane was synthesized by heterofunctional condensation. The effect of hexafluoroalkyl substituents at the silicon atom on the reactivity of the siloxane bonds has been studied.

引用

页码：690 / 693

页数：3

共 17 条

[1]

Khoroshavina Yu.V.(2011)undefined Russ. J. Gen. Chem. 81 576-undefined

[2]

Nikolaev G.A.(1961)undefined J. Org. Chem. 26 2464-undefined

[3]

Haggerty W.J.(1968)undefined Vysokomol. Soedin A. 11 1362-undefined

[4]

Breed L.W.(1970)undefined Vysokomol. Soedin A. 12 1683-undefined

[5]

Andrianov K.A.(1972)undefined Reakts. Sposobn. Org. Soed. (Tartu) 9 805-undefined

[6]

Andrianov K.A.(1965)undefined Zh. Obshch. Khim. 35 1060-undefined

[7]

Petrova I.M.(1962)undefined J. Am. Chem. Soc. 84 3548-undefined

[8]

Yakushkina S.E.(undefined)undefined undefined undefined undefined-undefined

[9]

Mileshkevich V.P.(undefined)undefined undefined undefined undefined-undefined

[10]

Nikolaev G.A.(undefined)undefined undefined undefined undefined-undefined

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