Steady State Thermodynamics

被引：0
作者：
Shin-ichi Sasa
Hal Tasaki
机构：
[1] University of Tokyo,Department of Pure and Applied Sciences
[2] Gakushuin University,Department of Physics
来源：
Journal of Statistical Physics | 2006年 / 125卷
关键词：
nonequilibrium steady state; thermodynamics; fluctuation ;
D O I：
暂无
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学科分类号：
摘要：
The present paper reports our attempt to search for a new universal framework in nonequilibrium physics. We propose a thermodynamic formalism that is expected to apply to a large class of nonequilibrium steady states including a heat conducting fluid, a sheared fluid, and an electrically conducting fluid. We call our theory steady state thermodynamics (SST) after Oono and Paniconi's original proposal. The construction of SST is based on a careful examination of how the basic notions in thermodynamics should be modified in nonequilibrium steady states. We define all thermodynamic quantities through operational procedures which can be (in principle) realized experimentally. Based on SST thus constructed, we make some nontrivial predictions, including an extension of Einstein's formula on density fluctuation, an extension of the minimum work principle, the existence of a new osmotic pressure of a purely nonequilibrium origin, and a shift of coexistence temperature. All these predictions may be checked experimentally to test SST for its quantitative validity.
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页码：125 / 224
页数：99
相关论文
共 136 条
[11]  
Onsager L.(1961)Variational principles in thermodynamics and statistical mechanics of irreversible processes Adv. Chem. Phys. 3 267-321
[12]  
Machlup S.(1967)Nonlinear Effects in the shear viscosity of critical mixture Prog. Theor. Phys. 38 1031-1051
[13]  
Hashitsume N.(1973)Theory of nonlinear transport processes: nonlinear shear viscosity and normal stress effects Phys. Rev. A 8 2048-2064
[14]  
Ono S.(1994)Generic long-range correlations in molecular fluids Ann. Rev. Phys. Chem. 45 213-239
[15]  
Yamada T.(1961)Memory Effects in irreversible thermodynamics Phys. Rev. 124 983-992
[16]  
Kawasaki K.(1965)Transport, collective motion, and Brownian motion Prog. Theor. Phys. 33 423-455
[17]  
Kawasaki K.(2000)Path-ensemble averages in systems driven far from equilibrium Phys. Rev. E 63 2361-2366
[18]  
Gunton J. D.(2003)Anomalous pressure in fluctuating shear flow Phys. Rev. E 67 065302(R)-142
[19]  
Dorfman J. R.(1978)Irreversible thermodynamics for quantum systems weakly coupled to thermal reservoirs Adv. Chem. Phys. 38 109-162
[20]  
Kirkpatrick T. R.(2002)Non-equilibrium steady states of finite quantum systems coupled to thermal reservoirs Comm. Math. Phys. 226 131-3831
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