Experimental and molecular-statistical investigation of adsorption of aminoadamantanes on graphitized thermal carbon black

被引：0
作者：
S. N. Yashkin
O. B. Grigor"eva
A. K. Buryak
机构：
[1] Samara State University,Institute of Physical Chemistry
[2] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2001年 / 50卷
关键词：
aminoadamantane isomers; adsorption; gas solid chromatography; graphitized thermal carbon black; Henry constant; heat of adsorption; nitrogen atom in the amino group; atom-atom potentials; “cage” effect;
D O I：
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摘要：
Thermodynamic characteristics of adsorption of some isomeric aminoadamantanes on graphitized thermal carbon black were determined by molecular-statistic calculations and gas-chromatographic measurements. The parameters of the potential function for the pairwise intermolecular interactions between nitrogen in saturated amines and carbon in graphite were calculated. The best agreement between the experimental and calculated Henry constants for 1-aminoadamantane is attained by introducting a correction taking into account the influence of the “cage” effect on α-substituents in the adamantane unit in the parameters of the ϕN...C(GTCB) atom-atom potential.
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页码：980 / 985
页数：5
相关论文
共 64 条
[1]  
Spasov A. A.(2000)undefined Khim.-Farm. Zhurn. 34 3-undefined
[2]  
Khamidova T. V.(1998)undefined Antiviral Research 37 83-undefined
[3]  
Bugaeva L. I.(1991)undefined Khim.-Farm. Zhurn. 25 46-undefined
[4]  
Morozov I. S.(1971)undefined Dokl. Akad. Nauk SSSR 198 984-undefined
[5]  
Scholtissek C.(1998)undefined Biochem. Pharmacol. 56 141-undefined
[6]  
Quack G.(1995)undefined Mov. Disord. 10 121-undefined
[7]  
Klenk H. D.(1977)undefined Vestn. Akad. Med. Nauk SSSR 2 77-undefined
[8]  
Webster R. G.(1999)undefined Rus. Zhurn. VICh/SPID i Rodstv. Probl. 3 56-undefined
[9]  
Klimochkin Y. N.(1999)undefined J. Org. Chem. 64 7208-undefined
[10]  
Moiseev I. K.(1988)undefined Zh. Analit. Khim. 43 328-undefined
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