Conductivities of the Ternary Systems Y(NO3)3+La(NO3)3+H2O, La(NO3)3+Ce(NO3)3+H2O, La(NO3)3+Nd(NO3)3+H2O and Their Binary Subsystems at Different Temperatures

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作者
Yu-Feng Hu
Chuan-Wei Jin
Jin-Zhu Zhang
Shan Ling
机构
[1] China University of Petroleum,State Key Laboratory of Heavy Oil Processing, High Pressure Fluid Phase Behavior and Property Research Laboratory
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关键词
Conductivity; Rare earth nitrates; Aqueous mixed solutions; Conductivity prediction;
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摘要
Electrical conductivities were measured for the ternary systems Y(NO3)3+La(NO3)3+H2O, La(NO3)3+Ce(NO3)3+H2O, La(NO3)3+Nd(NO3)3+H2O, and their binary subsystems Y(NO3)3+H2O, La(NO3)3+H2O, Ce(NO3)3+H2O, and Nd(NO3)3+H2O at (293.15, 298.15 and 308.15) K. The measured conductivities were used to test the generalized Young’s rule and the semi-ideal solution theory. The comparison results show that the generalized Young’s rule and the semi-ideal solution theory can yield good predictions for the conductivities of the ternary electrolyte solutions, implying that the conductivities of aqueous solutions of (1:3 + 1:3) electrolyte mixtures can be well predicted from those of their constituent binary solutions by the simple equations.
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页码:1447 / 1457
页数:10
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