New rhodamine derivative as OFF-ON fluorescent chemosensor for detection of Cu2+

被引：0
作者：
Xing Ma
Jun Liu
YuGuo Du
GuoHua Wei
DongBin Wei
机构：
[1] Chinese Academy of Sciences,State Key Laboratory of Environmental Chemistry and Ecotoxicology; Research Center for Eco
[2] Graduate University of Chinese Academy of Sciences,Environmental Sciences
来源：
Science China Chemistry | 2011年 / 54卷
关键词：
copper; fluorescent chemosensor; rhodamine; naked-eye detection;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel fluorescence probe for the detection of Cu2+ has been designed and synthesized, which is based on a ring-opening reaction of spirolactam triggered by Cu2+. This probe exhibits excellent Cu2+ ion selectivity as well as significant color changes visible to the naked eye at the concentration of 0.03 mM (ca. 2.0 mg/L), the WHO (World Health Organization) recommended level (2.0 mg/L) of Cu2+ ions in drinking water. This novel rhodamine-based fluorescence probe can be directly used to detect Cu2+ with satisfactory sensitivity and selectivity in aqueous solution.
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页码：1635 / 1639
页数：4
相关论文
共 85 条
[1]  
Gaggelli E.(2006)Copper homeostasis and neurodegerative disorders (Alzheimer’s, Prion, and Parkinson’s Diseases and Amyotrophic Lateral Sclerosis) Chem Rev 106 1995-2044
[2]  
Kozlowski H.(1990)The DNA and Cu binding functions of ACE1 are interdigitated within a single domain New Biol 2 544-555
[3]  
Valensin D.(1996)The amyloid precursor protein of Alzheimer’s disease in the reduction of copper(II) to copper(I) Science 271 1406-1409
[4]  
Valensin G.(2004)A kinetic study on the distribution of Cu(II)-ions between albumin and transferring BioMetals 17 111-113
[5]  
Hu S.(2003)Fluorogenic and chromogenic chemosensors and reagents for anions Chem Rev 103 4419-4476
[6]  
Furst P.(2005)A highly selective fluorescent chemosensor for Pb J Am Chem Soc 127 10107-10111
[7]  
Hamer D.(2006) monitoring of mercury ions using a rhodamine-based molecular probe J Am Chem Soc 128 14150-14155
[8]  
Muthaup G.(2010)A thiophen-thioox-orhodamine conjugate fluorescent probe for detecting mercury in aqueous media and living cells Org Biomol Chem 8 4819-4822
[9]  
Schlicksupp A.(2006)A new rhodamine-based chemosensor exhibiting selective Fe(III)-amplified fluorescence Org Lett 8 1549-1552
[10]  
Hess L.(2007)Tuning the selectivity of two chemosensors to Fe(III) and Cr(III) Org Lett 9 4567-4570
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