Interaction between cationic monomer and sodium dodecyl sulfate in concentrated aqueous solutions: EPR spectroscopy and rotational viscometry

被引：0
作者：
Yu. V. Shulevich
M. V. Motyakin
Yu. A. Zakharova
E. G. Dukhanina
A. M. Wasserman
A. V. Navrotskii
I. A. Novakov
机构：
[1] Volgograd State Technical University,Semenov Institute of Chemical Physics
[2] Russian Academy of Sciences,Faculty of Chemistry
[3] Moscow State University,undefined
来源：
Colloid Journal | 2015年 / 77卷
关键词：
Sodium Dodecyl Sulfate; Colloid Journal; Spin Probe; Sodium Dodecyl Sulfate Concentration; Surfactant Micelle;
D O I：
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学科分类号：
摘要：
The interaction of a cationic monomer, trimethyl[methacryloxyethyl]ammonium methyl sulfate, with sodium dodecyl sulfate (SDS) has been studied in relatively concentrated solutions containing SDS (70–500 mM) and the monomer (from 7 mM to 2.5 M). The high concentrations of the components do not prevent the monomer from bonding to oppositely charged SDSs, which confirms the possibility in principle to polymerize ionic monomers through a template mechanism using micelles of oppositely charged surfactants as templates. The range of component ratios 0.5 ≤ [monomer]/[SDS] ≤ 2 is most promising for realization of the template mechanism of polymerization. The effect of SDS on the macroscopic and microscopic properties of the system significantly and to a maximum extent decreases upon a further rise in the relative concentration of the monomer.
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页码：108 / 114
页数：6
相关论文
共 39 条
[1]  
Polowinski S(2002)undefined Prog. Polym. Sci. 27 537-undefined
[2]  
Papisov IM(1997)undefined Polym. Sci., Ser. B 39 122-undefined
[3]  
Petzold G(2007)undefined Colloids Surf. A 298 139-undefined
[4]  
Mende M(2004)undefined Polym. Sci., Ser. A 46 451-undefined
[5]  
Kochurova N(2009)undefined Russ. J. Appl. Chem. 82 1582-undefined
[6]  
Kabanov VA(1999)undefined Colloids Surf. A 147 169-undefined
[7]  
Shulevich YuV(2009)undefined Colloid J. 71 672-undefined
[8]  
Nguen TKh(1994)undefined Usp. Khim. 63 391-undefined
[9]  
Navrotskii AV(2003)undefined Phys. Chem. Chem. Phys. 5 5271-undefined
[10]  
Novakov IA(1996)undefined J. Magn. Reson. A 120 155-undefined
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