Excess Molar Volumes for (Binary Mixtures of 1-Alkanol and 1-Alkene). I. The System 1-Alkanol + 1-Octene at 25°C

被引：0

作者：

Andrzej J. Treszczanowicz

Teresa Treszczanowicz

Teresa Kasprzycka-Guttman

Tomasz S. Pawłowski

机构：

[1] Polish Academy of Sciences,Department of Supramolecular Chemistry, Institute of Physical Chemistry

[2] Warsaw University,Department of Chemistry

来源：

Journal of Solution Chemistry | 2002年 / 31卷

关键词：

Excess molar volumes; 1-alkanol; 1-octene; hydrogen bonding; association;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Excess volumes measured at 25°C are reported for binary mixtures of the C3, C4, C6, C8, and C10 1-alkanols with 1-octene. In this series of mixtures, the excess-volume curves change from positive values over the whole concentration range for short-chain alkanols C3 and C4, to sigmoid for longer-chain alkanols (with positive values in the alkanol-rich region). The positive region decreases with increasing chain length of the 1-alkanol. Excess partial molar volumes of the components are calculated. The results are compared with those for mixtures of 1-alkanols with n-octane. The model of associated mixtures proposed by Treszczanowicz and Benson3 describes very well the size and shape of the excess volume for the class of systems considered.

引用

页码：455 / 466

页数：11

共 50 条

[21] Volumetric properties of piperidine + 1-alkanol binary liquid mixtures experimental results and application of Prigogine-Flory-Patterson theory
Boussebissi, Assia
Boukais-Belaribi, Ghenima
Belaribi, Farid Brahim
[J]. JOURNAL OF MOLECULAR LIQUIDS, 2014, 196 : 1 - 6
[22] Studies of viscosity and excess molar volume of binary mixtures 3.: 1-alkanol plus di-n-propylamine, and plus di-n-butylamine mixtures at 303.15 and 313.15 K
Oswal, SL
Desai, HS
[J]. FLUID PHASE EQUILIBRIA, 2001, 186 (1-2) : 81 - 102
[23] Excess molar enthalpy of 1-alkanol+1-octene mixtures at 298.15 K - Experimental results and theoretical description by means of the ERAS and TB models
Pawlowski, Tomasz S.
[J]. FLUID PHASE EQUILIBRIA, 2007, 262 (1-2) : 14 - 22
[24] Excess Molar Volumes of Binary Mixtures of 1-Heptanol or 1-Nonanol with n-Polyethers at 25°C
F. J. Arroyo
F. J. Carmona
I. García De La Fuente
J. A. González
J. C. Cobos
[J]. Journal of Solution Chemistry, 2000, 29 : 743 - 756
[25] Excess molar volumes of binary mixtures of 1-heptanol or 1-nonanol with n-polyethers at 25°C
Arroyo, FJ
Carmona, FJ
De La Fuente, IG
González, JA
Cobos, JC
[J]. JOURNAL OF SOLUTION CHEMISTRY, 2000, 29 (08) : 743 - 756
[26] Studies of viscosity and excess molar volume of binary mixtures - 2. Butylamine+1-alkanol mixtures at 303.15 and 313.15 K
Oswal, SL
Desai, HS
[J]. FLUID PHASE EQUILIBRIA, 1999, 161 (01) : 191 - 204
[27] Effect of alkyl group of 1-alkanol on molecular interactions of ethanoic acid mixtures: FT-IR spectroscopic and volumetric studies
Chandraiah, T.
Karlapudi, S.
Govinda, V.
Sreedhar, N. Y.
Bahadur, I.
[J]. JOURNAL OF MOLECULAR LIQUIDS, 2018, 255 : 354 - 363
[28] Intra- and Inter-molecular Interactions between 1-Alkanol and Benzonitrile: Computational and Thermodynamic Study
Karlapudi, Sreenivasulu
Govinda, Varadhi
Koralkar, Noval
Kumar, Kasibhatta Siva
Bahadur, Indra
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2023, 68 (11) : 2752 - 2766
[29] Prediction of the excess volume and isobaric thermal expansion for 1-alkanol plus n-alkane systems in terms of an association model with a Flory contribution term
Treszczanowicz, AJ
Treszczanowicz, T
[J]. FLUID PHASE EQUILIBRIA, 1997, 135 (02) : 179 - 192
[30] Characterization of 1-alkanol + strongly polar compound mixtures from thermophysical data and the application of the Kirkwood-Buff integrals and Kirkwood-Frohlich formalisms
Antonio Gonzalez, Juan
Hevia, Fernando
Felipe Sanz, Luis
Garcia De la Fuente, Isaias
Carlos Cobos, Jose
[J]. FLUID PHASE EQUILIBRIA, 2019, 492 : 41 - 54

← 1 2 3 4 5 →