Copolymerization of 1-Vinyl-4,5,6,7-tetrahydroindole with Vinyl Chloride in the Presence of a Radical Initiator

被引:0
作者
N. S. Shaglaeva
O. V. Lebedeva
A. I. Mikhaleva
G. A. Pirogova
R. G. Sultangareev
N. N. Chipanina
G. A. Gavrilova
机构
[1] Favorskii Irkutsk Institute of Chemistry,Siberian Division, Russian Academy of Sciences
来源
Russian Journal of Applied Chemistry | 2002年 / 75卷
关键词
Hydrogen; Chloride; Oligomerization; Vinyl; Copolymerization;
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摘要
Copolymerization of 1-vinyl-4,5,6,7-tetrahydroindole with vinyl chloride in the presence of azobis(isobutyronitrile) occurs as a two-step process. The copolymer is initially formed by the radical mechanism. Then, the eliminated hydrogen chloride initiates cationic oligomerization of 1-vinyl-4,5,6,7-tetrahydroindole, enriching the copolymer with units of this monomer.
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页码:1462 / 1464
页数:2
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