Synthesis and Structure of the Supramolecular Adduct Formed by the [Mo3S4(H2O)7Cl22+ Cluster Complex with Cucurbituril: {[Mo3S4(H2O)7Cl2](C36H36N24O12)} Cl2·10H2O

被引：0

作者：

E. V. Chubarova

D. G. Samsonenko

J. H. Platas

M. N. Sokolov

V. P. Fedin

机构：

[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch

[2] University of La Laguna,undefined

来源：

Journal of Structural Chemistry | 2004年 / 45卷

关键词：

molybdenum; cucurbituril; cluster;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Slow crystallization of an HCl solution containing cucurbituril (C36H36N24O12) and a triangular molybdenum cluster aqua complex [Mo3S4(aq)]4+ yielded a supramolecular adduct of { [Mo3S4(H2O)7Cl2]×(C36H36N24O12)Cl2·10H2O composition. The molecular and crystal structure of the adduct were established by single crystal X-ray diffraction. Monoclinic crystal system, space group P21/c, a = 21.4762(2) Å, b = 14.6853(1) Å, c = 24.6480(3) Å; β = 112.8366(5)°, Vcell = 7164.26(12) Å3, Z = 4, ρcalc = 1.725 g/cm3.

引用

页码：906 / 911

页数：5

共 14 条

[1]

Virovets A. V.(2002)undefined Zh. Strukt. Khim. 43 517-526

[2]

Gerasko O. A.(2002)undefined Usp. Khim. 71 841-860

[3]

Samsonenko D. G.(2000)undefined Inorg. Chem. 39 2227-2230

[4]

Fedin V. P.(1994)undefined J. Am. Chem. Soc. 116 3389-3398

[5]

Fedin V. P.(1905)undefined Justus Liebigs Ann. Chem. 339 1-37

[6]

Virovets A. V.(2003)undefined J. Appl. Cryst. 36 7-13

[7]

Sokolov M. N.(undefined)undefined undefined undefined undefined-undefined

[8]

Murata T.(undefined)undefined undefined undefined undefined-undefined

[9]

Mizobe Y.(undefined)undefined undefined undefined undefined-undefined

[10]

Gao H.(undefined)undefined undefined undefined undefined-undefined

← 1 2 →