Vibrationally Excited Ozone Relaxation by CO

被引：0
|
作者：
A. P. Torbin
A. A. Pershin
A. M. Mebel
V. N. Azyazov
机构：
[1] Russian Academy of Sciences,Samara Branch of the Lebedev Physical Institute
[2] Samara National Research University,undefined
[3] Florida International University.,undefined
来源：
Bulletin of the Lebedev Physics Institute | 2018年 / 45卷
关键词：
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Time profiles of ozone concentration after pulsed UV laser photolysis in the O2- O3-Ar-CO mixture, measured using time-resolved absorption spectroscopy, are presented. The experimental results show the dominance of the stabilization channel over the reactive one for the interaction between the vibrationally excited ozone molecule O3(υ) and carbon monoxide CO. The rate constant of the process O3(υ)+CO→O3 + CO, obtained by processing experimental data by the kinetic modeling method is (1.5 ± 0.2) · 10−13 cm3/s.
引用
收藏
页码：67 / 70
页数：3
相关论文
共 50 条
  • [31] Rotational Energy Relaxation Time for Vibrationally Excited Molecules
    Bechina, A. I.
    Kustova, E. V.
    VESTNIK ST PETERSBURG UNIVERSITY-MATHEMATICS, 2019, 52 (01) : 81 - 91
  • [32] NONLINEAR RELAXATION OF VIBRATIONALLY HIGHLY EXCITED FREON MOLECULES
    ACHASOV, OV
    BRUZZESE, R
    DELISIO, C
    SOLIMENO, S
    OPTICS COMMUNICATIONS, 1987, 64 (03) : 234 - 238
  • [33] COLLISIONAL RELAXATION OF VIBRATIONALLY EXCITED NO+(V) IONS
    FEDERER, W
    DOBLER, W
    HOWORKA, F
    LINDINGER, W
    DURUPFERGUSON, M
    FERGUSON, EE
    JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (03): : 1032 - 1038
  • [34] MECHANISM OF HETEROGENEOUS RELAXATION OF VIBRATIONALLY EXCITED NITROGEN MOLECULES
    EGOROV, VI
    GERSHENZ.YM
    ROZENSHT.VB
    UMANSKII, SY
    CHEMICAL PHYSICS LETTERS, 1973, 20 (01) : 77 - 80
  • [35] Relaxation of vibrationally excited reaction products in a crystal lattice
    A. V. Kalenskii
    A. A. Zvekov
    M. V. Anan’eva
    A. P. Borovikova
    Russian Journal of Physical Chemistry B, 2016, 10 : 191 - 196
  • [36] ENERGY RELAXATION PROCESSES OF VIBRATIONALLY EXCITED MOLECULES IN LIQUIDS
    SEILMEIER, A
    SPANNER, K
    LAUBEREAU, A
    KAISER, W
    OPTICS COMMUNICATIONS, 1976, 18 (01) : 194 - 194
  • [37] Relaxation of vibrationally excited reaction products in a crystal lattice
    Kalenskii, A. V.
    Zvekov, A. A.
    Anan'eva, M. V.
    Borovikova, A. P.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2016, 10 (02) : 191 - 196
  • [38] Rotational Energy Relaxation Time for Vibrationally Excited Molecules
    A. I. Bechina
    E. V. Kustova
    Vestnik St. Petersburg University, Mathematics, 2019, 52 : 81 - 91
  • [39] VIBRATIONALLY EXCITED OZONE IN PULSE RADIOLYSIS AND FLASH PHOTOLYSIS OF OXYGEN
    HOCHANADEL, CJ
    GHORMLEY, JA
    BOYLE, JW
    JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (06): : 2416 - +
  • [40] State-resolved collisional relaxation of highly vibrationally excited CsH by CO2
    Mu, Baoxia
    Cui, Xiuhua
    Shen, Yifan
    Dai, Kang
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 148 : 299 - 310
12345