Synthesis and reactivity of metal-containing monomers51. Synthesis and molecular structure of the cluster-containing complex [Rh6(CO)14(μ,η2-PPh2Ch2CH=CH2)]

被引：0
作者：
S. I. Pomogailo
I. I. Chuev
G. I. Dzhardimalieva
A. V. Yarmolenko
V. D. Makhaev
S. M. Aldoshin
A. D. Pomogailo
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 1999年 / 48卷
关键词：
cluster-containing complex; molecular structure; rhodium clusters; coordination; π-complex; synthesis;
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摘要：
The reaction of Rh6(CO)15MeCN with allyldiphenylphosphine under mild conditions afforded the cluster-containing complex [Rh6(CO)14(μ,η2-PPh2Ch2CH=CH2)]. Its molecular structure was characterized. The resulting complex is an octahedral Rh cluster with ten terminal and four μ3-bridging CO ligands. The average Rh−Rh distance is 2.762(2) Å. The unsaturated ligand is additionally coordinated to the metal center (Rh(4)–C(232), 2.37(1) Å; and Rh(4)–C(233), 2.32(2) Å) to form a π-bond.
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页码：1174 / 1177
页数：3
相关论文
共 45 条
  • [1] Shuvaev A. T.(1998)undefined Izv. Akad. Nauk, Ser. Khim. 47 1505-750
  • [2] Rozenberg A. S.(1997)undefined Usp. Khim. 66 750-387
  • [3] Dzhardimalieva G. I.(1993)undefined Izv. Akad. Nauk, Ser. Khim. 42 975-1
  • [4] Ivleva N. P.(9190)undefined Metalloorg. Khim. 3 387-1202
  • [5] Vlasenko V. G.(1987)undefined Coord. Chem. Revs. 76 1-189
  • [6] Nedoseikina T. I.(1963)undefined J. Am. Chem. Soc. 85 1202-137
  • [7] Lyubeznova T. A.(1992)undefined J. Organomet. Chem. 433 189-389
  • [8] Uflyand I. E.(1996)undefined J. Organomet. Chem. 508 137-128
  • [9] Pomogailo A. D.(1971)undefined J. Organomet. Chem. 27 389-undefined
  • [10] Pomogailo A. D.(1974)undefined Inorganic Syntheses 15 128-undefined
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