Extraction of vanadium(V) by N′,N′-dialkylhydrazides of carboxylic acids from acidic solutions

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作者
T. D. Batueva
V. I. Karmanov
机构
[1] Russian Academy of Sciences,Institute of Technical Chemistry, Ural Branch
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关键词
Kerosene; Tributyl Phosphate; Back Extraction; Optimal Extraction Condition; Sulfuric Acid Medium;
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摘要
Extraction of vanadium(V) with solutions of 2-ethylhexanoic acid N′,N′-dialkylhydrazides in kerosene from acidic media was studied. The optimal extraction conditions were determined depending on the concentrations of H2SO2, HCl, and the extraction agent; the composition of the recovered complexes was proposed. The conditions for back-extraction of vanadium(V) from the organic phase were studied. It was found that benzoic acid N′,N′-diheptylhydrazide did not recover vanadium(V) from acidic media.
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页码:986 / 990
页数:4
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