Chemical Synthesis of Niobium Diboride Nanosheets by a Solid-State Reaction Route

被引：0

作者：

Liangbiao Wang

Qianli Shen

Hengfei Qin

Dejian Zhao

Weiqiao Liu

Jianhua Sun

Binglong Zhu

Quanfa Zhou

机构：

[1] Jiangsu University of Technology,Jiangsu Key Laboratory of Precious Metals Chemistry and Engineering, School of Chemistry and Environment Engineering

来源：

Journal of Superhard Materials | 2018年 / 40卷

关键词：

solid state route; X-ray diffraction; niobium diboride; nanosheets; chemical synthesis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new process was developed to synthesize niobium diboride (NbB2) nanosheets with the dimension of about 500 nm and thickness of about 10 nm by using metal niobium, iodine and sodium borohydride as starting materials in an stainless steel autoclave at 700°C. Iodine was used to facilitate the exothermic reaction between metal niobium and sodium borohydride and the formation of NbB2. X-ray powder diffraction pattern indicated that the obtained product is hexagonal phase NbB2 with the calculated lattice constants a = 110 Å and c = 3.2929 Å. The obtained product was also studied by thermogravimetric analysis. It had good oxidation resistance below 400°C in air.

引用

页码：392 / 395

页数：3

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