Metal exchange of Cd(II) octaphenyltetraazaporphyrin with d-metal salts in organic solvents

被引:0
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作者
S. V. Zvezdina
N. Zh. Mamardashvili
O. I. Koifman
机构
[1] Russian Academy of Sciences,Krestov Institute of Solution Chemistry
[2] Ivanovo State University of Chemistry and Technology,Institute of Chemistry of Macroheterocyclic Compounds
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关键词
Porphyrin; Metal Exchange; Effective Rate Constant; Porphyrin Complex; Anionic Ligand;
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摘要
The metal exchange of Cd(II) octaphenyltetraazaporphyrin with CoCl2 and MnCl2 was studied by spectrophotometry in DMF and DMSO. The kinetic parameters of the metal exchange were determined. A possible stoichiometric reaction mechanism was proposed.
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页码:389 / 392
页数:3
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