An effective mean-field method for describing surface effects in polymer layers

被引：0

作者：

A. V. Maksimov

O. G. Maksimova

D. V. Diordiichuk

机构：

[1] Cherepovets State University,

[2] OJSC Seversteel,undefined

来源：

Bulletin of the Russian Academy of Sciences: Physics | 2013年 / 77卷 / 8期

关键词：

Polymer Chain; Metastable State; Phase Transition Point; Molecular Field; Consistency Equation;

D O I：

10.3103/S1062873813080224

中图分类号：

学科分类号：

摘要：

The peeling off of an adsorbed flexible macromolecule from a surface under the action of an effective mean field formed due to intermolecular interactions with the ends of other extended chains is considered. It is shown that there is a first order phase transition in the system that is accompanied by a rise of fluctuations, the existence of metastable states, and jumps of the extension and heat capacity of chains.

引用

页码：1073 / 1075

页数：2