Crystal structure of the ionic cluster complex (2,2′-bipyH2)2[Re4Se4(CN)12]·(2,2′-bipy)·7H2O

被引：0

作者：

Ya. M. Gaifulin

A. I. Smolentsev

Yu. V. Mironov

机构：

[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch

[2] Novosibirsk State University,undefined

来源：

Journal of Structural Chemistry | 2014年 / 55卷

关键词：

rhenium; cubane cluster complex; bipyridylium cation; crystal structure;

D O I：

暂无

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学科分类号：

摘要：

A rhenium cluster complex (2,2′-bipyH2)2[Re4Se4(CN)12] · (2,2′-bipy)·7H2O (1) is obtained and characterized. The compound crystallizes in a monoclinic space group C2/c with the unit cell parameters: a = 16.9191(6) Å, b = 18.7458(6) Å, c = 19.0139(5) Å, β = 108.568(1)°, V = 5716.6(3) Å3, Z = 4, dx = 2.291 g/cm3. The crystal structure is a packing of bipyridylium cations (2,2′-bipyH2)2+, cluster anions [Re4Se4(CN)12]4−, bipyridyl molecules, and crystal water molecules, which are linked together by a system of hydrogen bonds.

引用

页码：920 / 922

页数：2

共 57 条

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