Controlled polymerization of methyl methacrylate in the presence of an FeCl3-complexing agent system

被引：0
作者：
S. A. Bulgakova
E. S. Tumakova
Yu. D. Semchikov
机构：
[1] Nizhni Novgorod State University,Research Institute of Chemistry
[2] Nizhni Novgorod State University,undefined
来源：
Polymer Science Series B | 2009年 / 51卷
关键词：
PMMA; Polymer Science Series; ATRP; Radical Polymerization; Methyl Methacrylate;
D O I：
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学科分类号：
摘要：
The controlled polymerization of methyl methacrylate in DMF with participation of FeCl3 and ligands (acrylamide, 1,1,1,3,3,3-hexamethyldisilazane, citric acid, and sulfosalicylic acid) has been studied. It has been shown for the first time that DMF ensures the polymerization of methyl methacrylate in the controlled mode without any other complexing agents. As temperature increases, the rate of the process and the polydispersity of PMMA increase.
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