Yperite-free method for the synthesis of polydentate sulfur-containing ligands

被引：0

作者：

Grabelnykh, V. A. ^{[1
]}

Vilms, A. I. ^{[2
]}

Bezborodov, V. A. ^{[2
]}

Korchevin, N. A. ^{[1
]}

Nalybaeva, A. M. ^{[3
]}

Oborina, E. N. ^{[1
]}

Katerinich, M. D. ^{[1
]}

Rozentsveig, I. B. ^{[1
,2
]}

Adamovich, S. N. ^{[1
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, 1 Ul Favorskogo, Irkutsk 664033, Russia

[2] Irkutsk State Univ, 1 Ul K Marksa, Irkutsk 664003, Russia

[3] DV Sokolsky Inst Fuel Catalysis & Electrochem, 142 Ul D Kunaeva, Alma Ata 050010, Kazakhstan

来源：

RUSSIAN CHEMICAL BULLETIN | 2024年 / 73卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

sulfur-containing polydentate ligands; 1,2-dichloroethane; polysulfide oligomers; hydrazine hydrate-KOH system; mass spectrometry; COMPLEXES;

D O I：

10.1007/s11172-024-4185-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sulfur-containing oligomers comprising C-S-C and C-S-S-C moieties were syntesized via the condensation of 1,2-dichloroethane with a mixture of potassium sulfide and disulfide. Cleavage of disulfide bonds in these oligomers with the hydrazine hydrate-KOH system led to the formation of alpha,omega-potassium dithiolates containing several ethylene sulfide S-C-C-S moieties in the chain. Alkylation of the dithiolates with iodomethane allowed obtaining compounds containing monosulfide moieties. Such compounds can be used as extractants, sorbents, and catalysts and can find applications in various fields, including microbiology, biotechnology, medicine, and agriculture.

引用

页码：738 / 742

页数：5

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