Tetra-n-butylammonium bromide-thiourea (1/2), a layer-type inclusion compound

被引：0
|
作者：
Mei Shi
Jin-Nan Zhang
Qi Li
机构：
[1] Beijing Normal University,Department of Chemistry
[2] Capital University of Medical Science,Department of Chemistry
来源：
Journal of Chemical Crystallography | 2003年 / 33卷
关键词：
Thiourea; host lattice; hydrogen-bonding; crystal structure;
D O I：
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学科分类号：
摘要：
The inclusion compound built of tetra-n-butylammonium bromide-thiourea (1/2), [(n-C4H9)4N+Br−⋅2(NH2)2CS], has been prepared and characterized by X-ray crystallography. The compound crystalline in orthorhombic space group Pbca, with a = 16.872(6) Å, b = 17.214(6) Å, c = 18.561(6) Å, V = 5390(3) Å3, Z = 8. The compound features a sandwich-like crystal structure built up from planar layers. In the crystal structure, zigzag hydrogen-bonded thiourea ribbons are linked by bromide anions to generate puckered layers matching the (100) planes, and the (n-C4H9)4N+ cations occupy the intervening space.
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页码：831 / 837
页数：6
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