Electrochemical degradation of spent tributyl phosphate extractant by a boron-doped diamond anode

被引：0
|
作者：
Yuqin Zhou
Pan Yang
Yang Pu
Sensen Xuan
Pohui Wang
Yaping Zhang
机构：
[1] Southwest University of Science and Technology,School of Materials Science and Engineering
来源：
Journal of Radioanalytical and Nuclear Chemistry | 2018年 / 315卷
关键词：
Tributyl phosphate; Boron-doped diamond anode; Electrochemical degradation; COD removal ratio; Energy consumption;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The effects of the main operation variables on the electrochemical oxidation of simulated tributyl phosphate (TBP) waste by a boron-doped diamond anode are individually studied. The optimum operating conditions are obtained as follows: 4 g L−1 initial TBP concentration, 180 min degradation time, 40 mA cm−2 current density, 0.5 mol L−1 Na2SO4 as the supporting electrolyte, and unadjusted pH of the aqueous phase. Under such conditions, a chemical oxygen demand (COD) removal ratio of 82.3% is achieved, and the energy consumption is 26.16 kWh m−3. A degradation mechanism of TBP is tentatively proposed.
引用
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页码：29 / 37
页数：8
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