Response for Comment on Solubility of Baicalein in Different Solvents from (287 to 323) K

被引:0
作者
Jianguo Wu
机构
[1] Huaiyin Normal University,Jiangsu Key Laboratory for Eco
[2] Huaiyin Normal University,Agricultural Biotechnology Around Hongze Lake, School of Life Science
来源
International Journal of Thermophysics | 2019年 / 40卷
关键词
Apelblat equation; Baicalein; Solubility; van’t Hoff equation;
D O I
暂无
中图分类号
学科分类号
摘要
Xu and Zhao found the inconsistencies between the equations’ parameters and the solubility data by Wu et al. (Int J Thermophys 35: 1465–1475, 2014) for describing solubility of baicalein in different solvents from (287 to 323) K with the modified Apelblat equation and van’t Hoff equation. The inconsistencies were solved by further modifying the Apelblat equations as Eq. (2) and reevaluating the parameters of van’t Hoff equation listed as Table 1.Table 1Dissolution enthalpy and entropy of baicalein in different solvents according to the van’t Hoff equationSolventΔHS\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \Delta H_{S} $$\end{document}(KJ·mol−1)ΔSS\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ \Delta S_{S} $$\end{document}(J·mol−1·K−1)rrmsd × 105R2Methanol4.88− 41.250.870.985Ethanol8.04− 29.663.260.943n-propanol12.94− 13.201.790.994Propan-2-ol7.27− 34.571.290.980n-butanol10.35− 19.931.850.993Isobutanol11.86− 15.942.340.9891,3-Propanediol3.49− 43.631.040.976Ethyl acetate12.01− 12.622.130.996
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  • [1] Wu JG(2014)undefined Int. J. Thermophys. 35 1465-undefined
  • [2] Gu LW(undefined)undefined undefined undefined undefined-undefined
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  • [4] Tao LJ(undefined)undefined undefined undefined undefined-undefined
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