Synthesis, Crystal Structure, Luminescence, and Magnetic Properties of a New 4d–4f Heterometallic Architecture Based on Pyridine-3,4-Dicarboxylic Acid

被引：0
作者：
Guang-Xiang Liu
机构：
[1] Nanjing Xiaozhuang University,School of Biochemical and Environmental Engineering
来源：
Journal of Cluster Science | 2013年 / 24卷
关键词：
Heterometallic coordination polymer; Pyridine-3,4-dicarboxylic acid; Crystal structure; Luminescence; Magnetism;
D O I：
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学科分类号：
摘要：
A 4d–4f heterometallic coordination polymer, [AgEu(pydc)2]·2H2O (1) (H2pydc = pyridine-3,4-dicarboxylic acid), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a three-dimensional framework containing one-dimensional (1D) channels occupied by free water molecules, which is constructed from 1D inorganic heterometallic chains and linear pydc linkers. After removal of the water molecules from complex 1, the remaining material has high thermal stability. Moreover, the photoluminescence, and magnetic properties of 1 were also investigated.
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页码：787 / 798
页数：11
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