Crystal structure of the ionic complex [(VCl4)+(SbCl6)–]2(VCl4)

被引：0
作者：
S. I. Troyanov
机构：
[1] M.V. Lomonosov Moscow State University,Chemistry Department
来源：
Russian Journal of Inorganic Chemistry | 2015年 / 60卷
关键词：
Vanadium; Fullerene; Ionic Complex; Vanadium Atom; NOCl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Partial oxidation of vanadium(IV) to vanadium(V), which is stabilized due the formation of (VCl4)+ cations, occurs in the system VCl4–SbCl5 at heating. In the crystal structure of [(VCl4)+(SbCl6)–]2(VCl4), the layers of (SbCl6)– anions alternate with the layers containing both (VCl4)+ cations and neutral VCl4 molecules.
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页码：1041 / 1043
页数：2
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