Co(II) Catalyzed Solvent Free Auto-Oxidation of Methylbenzenes to Substituted Benzoic Acids Under Phase Transfer Conditions

被引：1
作者：
Nimer Taha
Mandan Chidambaram
Jihad Dakka
Yoel Sasson
机构：
[1] The Hebrew University of Jerusalem,Casali Institute of Applied Chemistry
[2] University of California,Energy Biosciences Institute
来源：
Catalysis Letters | 2009年 / 129卷
关键词：
Solvent free oxidation; Auto-oxidation; Substituted benzoic acid; Didecyldimethylammonium bromide; Cobalt chloride; Phase transfer catalysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel methodology for the solvent free auto-oxidation of methylbenzenes under mild conditions is disclosed. The new scheme is based on a combination of metallic salt (cobalt chloride) and a quaternary ammonium phase transfer catalyst (didecyldimethylammonium bromide) which together form a complex soluble catalyst in the organic phase. Major reaction parameters are studied and optimized and the procedure is applied for the conversion of several substituted toluenes to the corresponding benzoic acids in excellent isolated yields.
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页码：358 / 362
页数：4
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