Generation of silver and lead chromate nanoparticles in Triton N-42 and AOT reversed-micellar solutions

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作者
M. G. Demidova
A. I. Bulavchenko
A. V. Alekseev
机构
[1] Novosibirsk State University,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Russian Academy of Sciences,undefined
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Plasmon Band; Solubilization Capacity; Potassium Chromate; Lead Chromate; Metal Chromate;
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摘要
A process is proposed for manufacturing silver and lead nanoparticles in Triton N-42 and AOT solutions in decane. The completion of nanoparticle formation and solution stability were studied spectrophotometrically as functions of the parameters of reversed-micellar systems (the nature and proportion of the surfactant, solubilization capacity, reagent concentrations, and their ratios). Atomic absorption spectroscopy (AAS) and X-ray powder diffraction (XRD) showed that the nanoparticles isolated from Triton N-42 and AOT solutions compositionally correspond to and are isostructural to Ag2CrO4 and PbCrO4. Mean nanoparticle sizes are 15–30 nm as determined by transmission electron microscopy (TEM).
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页码:1446 / 1454
页数:8
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