DSC study of stabilizing effect of antioxidant mixtures in styrene-butadiene rubber

被引:0
作者
Zuzana Cibulková
Andrea Černá
Peter Šimon
Ján Uhlár
Karol Kosár
Peter Lehocký
机构
[1] Slovak University of Technology,Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology
[2] Research Institute of Chemical Technology (VUCHT a.s.),undefined
来源
Journal of Thermal Analysis and Calorimetry | 2012年 / 108卷
关键词
Styrene-butadiene rubber; Antioxidants; DSC; Synergism;
D O I
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中图分类号
学科分类号
摘要
The type of cooperation between antioxidants in the binary mixtures of four substituted diphenylamines and phenotiazine in the stabilization of styrene-butadiene rubber has been tested. Thermooxidation of the samples has been studied by differential scanning calorimetry under non-isothermal conditions. The protection factors of the individual stabilizers and their mixtures were determined. The synergy factors were applied to asses the type of cooperation of antioxidants in the mixtures. From their values it can be concluded that the type of cooperation depends on temperature. The highest synergistic effect has been observed for the mixture of phenotiazine and [4-(1-methyl-1-phenyl-ethyl)-phenyl]-phenylamine.
引用
收藏
页码:415 / 419
页数:4
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