Synthesis, crystal structure and thermal properties of [Co(NH 3)5Cl]MO4 (M = Mo, W)

被引：6
|
作者：
Shusharina E.A. [1 ]
Khranenko S.P. [1 ]
Plusnin P.E. [1 ,3 ]
Kardash T.Yu. [2 ]
Gromilov S.A. [1 ,3 ]
机构：
[1] A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
[2] G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
[3] Novosibirsk State University, SEC Nanosystems and Advanced Materials
来源：
Journal of Structural Chemistry | 2011年 / 52卷 / 5期
基金：
俄罗斯基础研究基金会;
关键词：
Cobalt; Complex salt; Crystal chemistry; Molybdenum; Single crystal X-ray diffraction; Thermal properties; Tungsten;
D O I：
10.1134/S0022476611050118
中图分类号：
学科分类号：
摘要：
Crystal structures of [Co(NH3)5Cl]MoO4 and [Co(NH3)5Cl]WO4 complex salts are determined by single crystal X-ray diffraction. It is demonstrated for both salts that within the temperature range T = -123-20°C there is a negative thermal expansion (about 0.26%) towards the c axis of the orthorhombic unit cell (Pnma space group). Thermal properties of the salts are investigated. The phase composition of the products obtained on heating the salts in different gas atmospheres is studied. Original Russian Text Copyright © 2011 by E. A. Shusharina, S. P. Khranenko, P. E. Plusnin, T. Yu. Kardash, and S. A. Gromilov.
引用
收藏
页码：918 / 923
页数：5
相关论文
共 50 条
  • [41] Binary Complexes [M(NH3)5Cl][PdCl4] · H2O (M = Rh, Co): Crystal Structure of [Rh(NH3)5Cl][PdCl4] · H2O
    S. V. Korenev
    Yu. V. Shubin
    S. A. Gromilov
    I. A. Baidina
    T. V. Basova
    Journal of Structural Chemistry, 2002, 43 : 643 - 648
  • [42] SYNTHESIS AND CRYSTAL STRUCTURE OF THE Mo(O) TRINUCLEAR COMPLEXES: (Et4N)2[(CO)4Mo(μ-S)2-M(μ-S)2Mo(CO)4] (Ⅰ: M=Mo, Ⅱ: M=W)
    萧泰
    余佩华
    庄伯涛
    Chinese Science Bulletin, 1992, (19) : 1669 - 1670
  • [43] Thermolysis of Cs9 MO4 (M = In, Sc): Synthesis, Crystal Structure, Chemical Bonding, and Reactivity of the Subvalent Oxidometalates Cs7 MO4 (M = In, Sc)
    Zaytseva, Irina
    Waldmann, Hannah
    Linhart, Markus Philipp
    Ungermann, Sabine Ispas
    Tambornino, Frank
    Hoch, Constantin
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (42) : 29123 - 29134
  • [44] SCF-MO CALCULATION OF ELECTRONIC ENERGY LEVELS OF CO[NH3)5CL]2+
    SAHINI, VE
    TUFOI, V
    REVUE ROUMAINE DE CHIMIE, 1971, 16 (06) : 789 - &
  • [45] Crystal structure of [Co(NH3)5Cl]2(W10O32)·4H2O
    N. V. Kuratieva
    S. P. Khranenko
    S. A. Gromilov
    Journal of Structural Chemistry, 2014, 55 : 285 - 289
  • [46] Crystal structure of [Co(NH3)5Cl]2(W10O32)•4H2O
    Kuratieva, N. V.
    Khranenko, S. P.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (02) : 285 - 289
  • [47] Syntheses, structures and characterizations of Rb3Na(MO4)2 (M = Mo, W) crystals
    Bai, Chunyan
    Lei, Chen
    Pan, Shilie
    Wang, Ying
    Yang, Zhihua
    Han, Shujuan
    Yu, Hongwei
    Yang, Yun
    Zhang, Fangyuan
    SOLID STATE SCIENCES, 2014, 33 : 32 - 37
  • [48] Crystal structure and thermal properties of [Pt(NH3)5Cl][ReCl6]Cl·H2O
    A. V. Zadesenets
    I. V. Korol’kov
    S. A. Gromilov
    Journal of Structural Chemistry, 2013, 54 : 201 - 205
  • [49] Crystal structure and thermal properties of [Pt(NH3)5Cl][ReCl6]Cl•H2O
    Zadesenets, A. V.
    Korol'kov, I. V.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (01) : 201 - 205
  • [50] FORMATION OF THE (MO(S2)2) (M = MO, W) MOIETY BY A MO4(2)-POLYSULFIDE REACTION - SYNTHESIS AND STRUCTURE OF MO(S2)2(BPY)
    CHAKRABARTY, PK
    BHATTACHARYA, S
    PIERPONT, CG
    BHATTACHARYYA, R
    INORGANIC CHEMISTRY, 1992, 31 (17) : 3573 - 3577
12345