Synthesis, crystal structure and thermal properties of [Co(NH 3)5Cl]MO4 (M = Mo, W)

被引：6
|
作者：
Shusharina E.A. [1 ]
Khranenko S.P. [1 ]
Plusnin P.E. [1 ,3 ]
Kardash T.Yu. [2 ]
Gromilov S.A. [1 ,3 ]
机构：
[1] A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
[2] G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
[3] Novosibirsk State University, SEC Nanosystems and Advanced Materials
来源：
Journal of Structural Chemistry | 2011年 / 52卷 / 5期
基金：
俄罗斯基础研究基金会;
关键词：
Cobalt; Complex salt; Crystal chemistry; Molybdenum; Single crystal X-ray diffraction; Thermal properties; Tungsten;
D O I：
10.1134/S0022476611050118
中图分类号：
学科分类号：
摘要：
Crystal structures of [Co(NH3)5Cl]MoO4 and [Co(NH3)5Cl]WO4 complex salts are determined by single crystal X-ray diffraction. It is demonstrated for both salts that within the temperature range T = -123-20°C there is a negative thermal expansion (about 0.26%) towards the c axis of the orthorhombic unit cell (Pnma space group). Thermal properties of the salts are investigated. The phase composition of the products obtained on heating the salts in different gas atmospheres is studied. Original Russian Text Copyright © 2011 by E. A. Shusharina, S. P. Khranenko, P. E. Plusnin, T. Yu. Kardash, and S. A. Gromilov.
引用
收藏
页码：918 / 923
页数：5
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