La Modified Fe–Mn/TiO2 Catalysts to Improve SO2 Resistance for NH3-SCR at Low-Temperature

被引:0
|
作者
Xinxin Hou
Hongping Chen
Yinghua Liang
Yonglin Wei
Zeqing Li
机构
[1] North China University of Science and Technology,College of Chemical Engineering
[2] Xinjiang University of Science and Technology,Department of Chemical Engineering
来源
关键词
NH; -SCR; Low temperature; Fe–Mn/TiO; catalyst; La modification; SO; resistance;
D O I
暂无
中图分类号
学科分类号
摘要
La modified TiO2 prepared by sol–gel method as the support of Fe–Mn/TiO2(xLa) catalyst significantly improved SO2 resistance. La inhibited the growth of TiO2 particle, and led to the obvious layered structure of TiO2 and more mesopores, which accelerated the decomposition of ammonium sulfate. The increase of Brønsted acid sites and the electron transfer between La and active components Fe and Mn in La doped catalysts inhibit the adsorption and oxidation of SO2 on the catalyst, thus improving the SO2 resistance.
引用
收藏
页码:291 / 299
页数:8
相关论文
共 50 条
  • [31] Byproduct Analysis of SO2 Poisoning on NH3-SCR over MnFe/TiO2 Catalysts at Medium to Low Temperatures
    Lee, Tsungyu
    Bai, Hsunling
    CATALYSTS, 2019, 9 (03):
  • [32] The effect of dopants (Fe, Al) on the low-temperature activity and SO2 tolerance in solvothermally synthesized MnOx NH3-SCR catalysts
    Li, Huirong
    Schill, Leonhard
    Gao, Qi
    Mossin, Susanne
    Riisager, Anders
    FUEL, 2024, 358
  • [33] Mechanism of Ce-Modified Birnessite-MnO2 in Promoting SO2 Poisoning Resistance for Low-Temperature NH3-SCR
    Fang, Xue
    Liu, Yongjun
    Cheng, Yan
    Cen, Wanglai
    ACS CATALYSIS, 2021, 11 (07): : 4125 - 4135
  • [34] DRIFT Study of the SO2 Effect on Low-Temperature SCR Reaction over Fe-Mn/TiO2
    Jiang, B. Q.
    Wu, Z. B.
    Liu, Y.
    Lee, S. C.
    Ho, W. K.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (11): : 4961 - 4965
  • [35] New Insight into SO2 Poisoning and Regeneration of CeO2-WO3/TiO2 and V2O5-WO3/TiO2 Catalysts for Low-Temperature NH3-SCR
    Xu, Liwen
    Wang, Chizhong
    Chang, Huazhen
    Wu, Qingru
    Zhang, Tao
    Li, Junhua
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2018, 52 (12) : 7064 - 7071
  • [36] The influence of CNTs addition on Mn-Ce/TiO2 catalyst for low-temperature NH3-SCR of NO
    Youn, Jae-Rang
    Kim, Min-Jae
    Lee, Seung-Jae
    Ryu, In-Soo
    Yoon, Hyung Chul
    Jeong, Soon Kwan
    Lee, Kyubock
    Jeon, Sang Goo
    CATALYSIS COMMUNICATIONS, 2021, 152 (152)
  • [37] Preparation of Mn/TiO2 catalysts using recovered manganese from spent alkaline batteries for low-temperature NH3-SCR
    Jan, Jenyu
    Chang, Chung-Liang
    Chang, Sue -min
    JOURNAL OF HAZARDOUS MATERIALS, 2024, 472
  • [38] Effect of calcination temperature on low-temperature NH3-SCR activity and the resistance of SO2 with or without H2O over Fe-Mn-Zr catalyst
    Fang, Ningjie
    Guo, Jiaxiu
    Shu, Song
    Luo, Hongdi
    Li, Jianjun
    Chu, Yinghao
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2018, 93 : 277 - 288
  • [39] Low-temperature NH3-SCR of NOx over MnCeOx/TiO2 catalyst: Enhanced activity and SO2 tolerance by modifying TiO2 with Al2O3
    Li, Gang
    Mao, Dongsen
    Chao, Mengxi
    Li, Gehua
    Yu, Jun
    Guo, Xiaoming
    JOURNAL OF RARE EARTHS, 2021, 39 (07) : 805 - 816
  • [40] Low-temperature NH3-SCR of NOx over MnCeOx/TiO2 catalyst:Enhanced activity and SO2 tolerance by modifying TiO2 with Al2O3
    Gang Li
    Dongsen Mao
    Mengxi Chao
    Gehua Li
    Jun Yu
    Xiaoming Guo
    Journal of Rare Earths, 2021, 39 (07) : 805 - 816