Synthesis and Characterization of a New Noncentrosymmetric Dihydrogenmonophosphate [C12H13N2O]H2PO4

被引：0
作者：
Sami Soukrata
Mohamed Belhouchet
Tahar Mhiri
机构：
[1] Université de Sfax,Laboratoire Physico
来源：
Journal of Cluster Science | 2015年 / 26卷
关键词：
Inorganic compounds; Chemical synthesis; Infrared and NMR spectroscopy; Thermal analysis; Electrical conductivity;
D O I：
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学科分类号：
摘要：
The organic–inorganic hybrid material [C12H13N2O]H2PO4 has been synthesized at room temperature by slow evaporation. The compound crystallizes in the noncentrosymmetric orthorhombic space group P212121 with the lattice parameters a = 4.75 (5) Å, b = 10.26 (5) Å, c = 27.09 (3) Å, Z = 4 and V = 1323.3 (2) Å3. The crystal structure has been determined and refined to R1 = 0.047 and wR2 = 0.120 using 2870 independent reflections. The atomic arrangement can be described by infinite anionic chains running parallel to the a axis. The organic cations are linked to the inorganic chains by hydrogen bonds so as to build a two-dimensional network. The infrared spectroscopy confirms the presence of the organic group and the anionic entities. Concerning the differential scanning calorimetry, it revealed one phase transition at 71 °C. Thermal analysis was performed to study its thermal stability. Besides, the impedance spectroscopy study, reported in the sample, reveals that the conduction in the material is due to a Grotthus mechanism.
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页码：835 / 849
页数：14
相关论文
共 99 条
[21]  
Srdanov VI(1987)undefined Chem. Phys. Letters 139 96-114
[22]  
Baoub L(1994)undefined J. Magn. Reson. 111 110-2133
[23]  
Jouini A(2006)undefined Elem 181 2117-77
[24]  
Rayes A(1986)undefined New York 1986 202-648
[25]  
Ben Nasr C(2003)undefined Thin Solid Films 426 68-10300
[26]  
Rzaigui M(1974)undefined J. Phys. Chem 78 639-187
[27]  
Kaabi K(1992)undefined Phys. Rev B.45 10292-2255
[28]  
Ben Nasr C(2002)undefined Solid State Ionics 147 181-undefined
[29]  
Rzaigui M(2005)undefined J. Solid State Chem 178 2247-undefined
[30]  
Kaabi K(undefined)undefined undefined undefined undefined-undefined
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