Molecular and crystal structure of 2-{(E)-[(4-Methylphenyl)imino]methyl}-4-nitrophenol: A redetermination

被引：0
作者：
Nihal Kan Kaynar
Hasan Tanak
Songul Şahin
Necmi Dege
Erbil Ağar
Metin Yavuz
机构：
[1] Ondokuz Mayıs University,Department of Physics, Faculty of Arts and Sciences
[2] Amasya University,Department of Physics, Faculty of Arts and Sciences
[3] Ondokuz Mayıs University,Department of Chemistry, Faculty of Arts and Sciences
来源：
Crystallography Reports | 2016年 / 61卷
关键词：
Schiff Base; Title Compound; Crystallography Report; Imino; Nitrophenol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The crystal structure of the title compound, C14H12N2O3, was recently determined as a mixture of its neutral (OH containing) and zwitterionic (NH containing) forms, in a 0.60 (4): 0.40 (4) ratio using the X-ray determination. In this study, the title compound has been characterized by FT-IR and X-ray diffraction. The redetermination showed that the title compound has only enol (OH) form because of lack of the NH stretching vibration in FT-IR spectrum. In addition, the molecular structure and tautomerism of the title compound have been discussed.
引用
收藏
页码：239 / 242
页数：3
相关论文
共 38 条
[1]  
Layer R. W.(1963)undefined Chem. Rev. 63 489-undefined
[2]  
Tanak H.(2009)undefined Acta Crystallogr. E 65 2949-undefined
[3]  
Yavuz M.(2001)undefined Bull. Korean Chem. Soc. 22 476-undefined
[4]  
Büyükgüngör O.(2013)undefined Acta Crystallogr. E 69 1085-undefined
[5]  
Aydoğan F.(2002)undefined J. Am. Chem. Soc. 124 6626-undefined
[6]  
Öcal N.(1987)undefined Tetrahedron 43 1345-undefined
[7]  
Turgut Z.(2009)undefined Acta Crystallogr. E 65 1572-undefined
[8]  
Tanak H.(2009)undefined Acta Crystallogr. E 65 3056-undefined
[9]  
Toğurman F.(2011)undefined Acta Crystallogr. E 67 2319-undefined
[10]  
Kalecik S.(1997)undefined J. Appl. Crystallogr. 30 565-undefined
1234