Solvent effect on the kinetics of the free-radical polymerization of styrene in the presence of fullerene C60

被引：0
|
作者：
R. Kh. Yumagulova
N. A. Medvedeva
S. I. Kuznetsov
V. A. Kraikin
S. V. Kolesov
机构：
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Scientific Center
来源：
Kinetics and Catalysis | 2014年 / 55卷
关键词：
Fullerene; Styrene; Induction Period; Chain Transfer; Chain Transfer Agent;
D O I：
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中图分类号：
学科分类号：
摘要：
The induction period in the kinetic curves of styrene polymerization in the presence of fullerene C60 was found to increase significantly at a solvent (benzene, toluene, ortho-dichlorobenzene, CCl4) concentration of ≥50 mol %. The free-radical polymerization rates of styrene in the presence of fullerene C60 and solvents, the ratio of chain propagation and termination rate constants kp/k01/2, and the stoichiometric inhibition coefficient were determined.
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页码：64 / 68
页数：4
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