Copolymerization of vinyl chloride with 1-(vinyloxyalkoxy)propylene oxides-2,3: Solvophobic effects of solvents

被引：0

作者：

T. V. Raskulova

L. I. Volkova

G. F. Myachina

A. K. Khaliullin

机构：

[1] Angarsk State Technical Academy,Favorsky Institute of Chemistry, Siberian Branch

[2] Russian Academy of Sciences,undefined

来源：

Polymer Science Series B | 2009年 / 51卷

关键词：

Polymer Science Series; Vinyl Chloride; Hydrodynamic Radius; Propylene Oxide; Reactivity Ratio;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The influence of solvophobic effects of aprotic solvents on the reactivity of 1-(vinyloxyalkoxy)propylene oxides-2,3 in free-radical copolymerization with vinyl chloride has been studied by dynamic light scattering. It has been shown that the association of copolymer macromolecules in aprotic solvents results in the reduced reactivity of 1-(vinyloxyalcoxy)propylene oxides-2,3. This effect can be explained by a decrease in their local concentration in the vicinity of the reaction center.

引用

页码：452 / 456

页数：4