Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(η2–C60)(CO)2(dpphen)(dbf)·0.63CS2] (dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate)

被引：0

作者：

Xiangjin Xie

Xianglin Jin

Kaluo Tang

机构：

[1] Peking University,Institute of Physical Chemistry, College of Chemistry and Molecular Engineering

来源：

Transition Metal Chemistry | 2003年 / 28卷

关键词：

Physical Chemistry; Crystal Structure; Inorganic Chemistry; Molybdenum; Fullerene;

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暂无

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学科分类号：

摘要：

The molybdenum complex [Mo(η2-C60)(CO)2(dpphen)(dbf)] (1) [dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate] has been prepared and structurally characterized by X-ray diffraction analysis. In the molecule of (1), the coordination geometry of the Mo atom is distorted octahedral with the phen (1,10-phenanthroline) group of dpphen and two CO groups in the equatorial plane. The Mo atom binds in an η2-fashion to the C—C bonds of C60and dbf. The two C—C bonds are almost mutually orthogonal.

引用

页码：741 / 744

页数：3