Specific features of the interaction of α- and γ-modifications of Al2O3 with carbonate and carbonate-chloride melts

被引:0
作者
I. D. Zakir’yanova
I. V. Korzun
V. A. Khokhlov
V. N. Dokutovich
E. V. Nikolaeva
B. D. Antonov
机构
[1] Russian Academy of Sciences,Institute of High
[2] Ural Federal University named after the first President of Russia B. N. Yeltsin,Temperature Electrochemistry, Ural Branch
来源
Russian Journal of Applied Chemistry | 2016年 / 89卷
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摘要
Data on reactivities of α- and γ-Al2O3 finely dispersed powders in a melted carbonate eutectic (Li2CO3–Na2CO3–K2CO3)eut and carbonate-chloride mixture 0.72(Li2CO3–Na2CO3–K2CO3)eut–0.28NaCl were obtained. The methods of synchronous thermal and X-ray phase analyses and Raman spectroscopy confirmed that, in contrast to γ-Al2O3, α-Al2O3 does not chemically interact with the melted carbonate eutectic and carbonate-chloride mixture (Li2CO3–Na2CO3–K2CO3)eut–NaCl can be recommended as a thickening agent for a carbonate fuel cell.
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页码:1066 / 1071
页数:5
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