Deuterium tracer studies on hydrotreating catalysts. 3. Influence of nickel on the rates of H2–D3 and H2S–D2 isotopic exchange

被引:0
|
作者
C. Thomas
L. Vivier
M. Lescanne
S. Kasztelan
G. Pérot
机构
[1] Université de Poitiers,Laboratoire de Catalyse en Chimie Organique, UMR 6503
[2] Institut Français du Pétrole,undefined
来源
Catalysis Letters | 1999年 / 58卷
关键词
sulfided molybdenum-on-alumina; nickel promoter; H–D isotopic exchange; H; –D; H; S–D; promoting effect; effect of pretreatment;
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摘要
The H–D isotopic exchange between H2 and D2 and between H2S and D2 was carried out at 80°C in a recycling reactor over a series of presulfided Mo/Al2O2 catalysts containing different amounts of nickel. Whatever the pretreatment procedure, it was found that the promoter had no significant effect on the rate of H–D exchange or on the amount of exchangeable hydrogen present on the catalysts.
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页码:33 / 35
页数:2
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