Amphiphilic Triblock Copolymers Based on Acrylic Acid and Alkyl Acrylates Synthesized via RAFT Polymerization-Induced Self-Assembly and RAFT Miniemulsion Polymerization

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作者：
Natalia Serkhacheva
Anna Plutalova
Elena Kozhunova
Nikolay Prokopov
Elena Chernikova
机构：
[1] Moscow Technological University,Lomonosov Institute of Fine Chemical Technologies
[2] Moscow State University,Faculty of Chemistry
[3] Moscow State University,Faculty of Physics
来源：
Polymer Science, Series B | 2018年 / 60卷
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摘要：
The aim of this research is to reveal the advantages and limitations of different heterophase polymerization methods, such as dispersion, emulsifier-free emulsion and miniemulsion polymerization, for the obtaining of in situ self-assembled amphiphilic triblock copolymer core-shell particles. In the present research, we addressed the problems of the controlled synthesis of two- and three-component amphiphilic ABA triblock copolymers based on acrylic acid, fluoroalkyl acrylates and butyl acrylate via polymerizationinduced self-assembly and reversible addition fragmentation chain transfer polymerization (RAFT) miniemulsion polymerization using symmetrical trithiocarbonates.
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页码：204 / 217
页数：13
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