Viscosities of Nonelectrolyte Liquid Mixtures Containing Acrylonitrile

被引:0
作者
S. L. Oswal
N. B. Patel
机构
[1] South Gujarat University,Department of Chemistry
来源
International Journal of Thermophysics | 2000年 / 21卷
关键词
acrylonitrile; alkyl acetate; binary liquid mixtures; correlating equations; dimethylformamide; dimethylacetamide; dimethyl sulphoxide; Gibbs energy of activation; molecular interactions; viscosities;
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摘要
The measurements of viscosity η are reported for seven binary mixtures of acrylonitrile (AN) with ethanenitrile (EN), methyl acetate (MA), ethyl acetate (EA), n-butyl acetate (BA), dimethylformamide (DMF), dimethylacetamide (DMA), and dimethyl sulphoxide (DMSO) at 303.15 K temperature. The viscosity data have been correlated with the equations of Grunberg and Nissan; Hind, McLaughlin, and Ubbelohde; Tamura and Kurata; Katti and Chaudhri; McAllister; Heric and Brewer; and of Auslaender. The relations between the viscosity deviations Δη, excess Gibbs energy of activation ΔG*E of viscous flow, and the intermolecular interaction in these mixtures are discussed.
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页码:999 / 1010
页数:11
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