3-Aminofuro[2,3-b]pyridines: Reaction with N-Chlorosuccinimide and Sodium Hypochlorite

被引:1
作者
Stroganova, T. A. [1 ]
Vasilin, V. K. [1 ]
Shitikov, N. V. [1 ]
Dmitrieva, I. G. [2 ]
Krapivin, G. D. [1 ]
机构
[1] Kuban State Technol Univ, Krasnodar 350072, Russia
[2] Kuban State Agrarian Univ, Krasnodar 350044, Russia
关键词
3-aminofuro[2,3-b]pyridines; chlorination; nucleophilic substitution; herbicide 2,4-D; antidote activity; DERIVATIVES; FUROPYRIDINES;
D O I
10.1134/S1070363224020075
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of aminoamides of the furo[2,3-b]pyridine series with an aqueous solution of sodium hypochlorite and N-chlorosuccinimide was studied. It was found that the chlorination reaction proceeds at position 2 of the furopyridine system, leading to previously unknown 3-imino-2-chlorofuro[2,3-b]pyridine-2-carboxamides. For some synthesized compounds, nucleophilic substitution reactions were investigated. Among the obtained substances, compounds were identified that have antidote activity against 2,4-D.
引用
收藏
页码:314 / 326
页数:13
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