Synthesis of 4-methylmorpholinium 6-amino-3,5-dicyano-4-(furan-2-yl)pyridine-2-thio(seleno)lates and 3-[aryl(hetaryl)]-2-cyanoprop-2-enethioamides by michael reaction

被引：0
作者：
I. V. Dyachenko
E. Yu. Ramazanova
V. D. Dyachenko
机构：
[1] Taras Shevchenko Lugansk National University,
[2] Donbas State Technical University,undefined
来源：
Russian Journal of Organic Chemistry | 2014年 / 50卷
关键词：
Malononitrile; Thioamide; BuOH; Methylidene; Michael Reaction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Michael reaction of dimethyl (furan-2-ylmethylidene)malonate with 2-cyanoethanethio(seleno)amides and 4-methylmorpholine afforded 4-methylmorpholinium 6-amino-3,5-dicyano-4-(furan-2-yl)pyridine-2-thio(seleno)lates via exchange of the CH acid components. Aryl(hetaryl)methylidenemalononitriles reacted with cyanoethanethioamide under analogous conditions to give 3-aryl(hetaryl)-2-cyanoprop-2-enethioamides which were converted into 3-aryl(hetaryl)-2-(1,3-thiazol-2-yl)prop-2-enenitriles according to Hantzsch.
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页码：1821 / 1825
页数：4
相关论文
共 31 条
  • [1] Sharanin YuA(1998)undefined Russ. Chem. Rev. 67 393-undefined
  • [2] Goncharenko MP(2007)undefined Russ. J. Org. Chem. 43 83-undefined
  • [3] Litvinov VP(1991)undefined Collect. Czech. Chem. Commun. 56 418-undefined
  • [4] Dyachenko IV(2004)undefined Russ. J. Org. Chem. 40 397-undefined
  • [5] Dyachenko VD(1981)undefined J. Heterocycl. Chem. 18 309-undefined
  • [6] Rusanov EB(1990)undefined Heterocycles 31 123-undefined
  • [7] Kada R(1992)undefined Z. Naturforsch., Teil B 47 1438-undefined
  • [8] Ilavasky D(1990)undefined Ukr. Khim. Zh. 56 65-undefined
  • [9] Goljer I(1994)undefined Zh. Org. Khim. 30 581-undefined
  • [10] Gaher P(1998)undefined Russ. J. Org. Chem. 34 554-undefined
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