Palladium(II, I, 0) Complexes in Catalytic Reactions of Oxidative Carbonylation

被引：0
作者：
O. N. Temkin
L. G. Bruk
机构：
[1] Lomonosov State Academy of Fine Chemical Technology,
来源：
Kinetics and Catalysis | 2003年 / 44卷
关键词：
Oxidation; Alcohol; Physical Chemistry; Carbonylation; Alkene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The mechanisms of carbonylation of alkenes, alkynes, and alcohols, including the mechanism of oxidative carbonylation of alkynes in the regime of self-oscillations catalyzed by Pd(II), Pd(I), or Pd(0) complexes, are analyzed. It is shown that the main reasons for the appearance of self-oscillations in the oxidation reactions are nonlinear and autocatalytic steps of generation and termination of active centers. The results of studying the functions of para-benzoquinone as an oxidant, ligand, and catalyst in the oxidative reactions are generalized. It is found that Pd(0) complexes with para-benzoquinone can catalyze oxidation reactions.
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页码：601 / 617
页数：16
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