Palladium(II, I, 0) Complexes in Catalytic Reactions of Oxidative Carbonylation

被引:0
作者
O. N. Temkin
L. G. Bruk
机构
[1] Lomonosov State Academy of Fine Chemical Technology,
来源
Kinetics and Catalysis | 2003年 / 44卷
关键词
Oxidation; Alcohol; Physical Chemistry; Carbonylation; Alkene;
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摘要
The mechanisms of carbonylation of alkenes, alkynes, and alcohols, including the mechanism of oxidative carbonylation of alkynes in the regime of self-oscillations catalyzed by Pd(II), Pd(I), or Pd(0) complexes, are analyzed. It is shown that the main reasons for the appearance of self-oscillations in the oxidation reactions are nonlinear and autocatalytic steps of generation and termination of active centers. The results of studying the functions of para-benzoquinone as an oxidant, ligand, and catalyst in the oxidative reactions are generalized. It is found that Pd(0) complexes with para-benzoquinone can catalyze oxidation reactions.
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页码:601 / 617
页数:16
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